https://www.socictopen.socict.org/files/original/854f04773ee8eb7cc9063dc2e0fd1dbd.pdf 43e4c910486d517c992d4c590cf517db Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Agricultura sostenible Description An account of the resource Dominio científico: Agricultura sostenible Text A resource consisting primarily of words for reading. Examples include books, letters, dissertations, poems, newspapers, articles, archives of mailing lists. Note that facsimiles or images of texts are still of the genre Text. Dublin Core The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/. Title A name given to the resource Insights into the Stability and Activity of MIL-53(Fe) in Solar Photocatalytic Oxidation Processes in Water Creator An entity primarily responsible for making the resource Jorge López, Ana M. Chávez, Ana Rey, Pedro M. Álvarez Description An account of the resource MIL-53(Fe) is a metal organic framework that has been recently considered a heterogeneous photocatalyst candidate for the degradation of water pollutants under visible or solar radiation, though stability studies are rather scarce in the literature. In this work, MIL-53(Fe) was successfully synthesized by a solvothermal method and fully characterized by X-ray diffraction (XRD), attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), N2 adsorption–desorption isotherm, Thermogravimetric analysis coupled with mass spectrometry (TGA-MS), UV-visible diffuse reflectance spectroscopy (DRS), elemental analysis and wavelength dispersive X-ray fluorescence (WDXRF). The effects of pH, temperature, solar radiation and the presence of oxidants (i.e., electron acceptors) such as ozone, persulfate and hydrogen peroxide on the stability of MIL-53(Fe) in water were investigated. The as-synthetized MIL-53(Fe) exhibited relatively good stability in water at pH 4 but suffered fast hydrolysis at alkaline conditions. At pH 4–5, temperature, radiation (solar and visible radiation) and oxidants exerted negative effect on the stability of the metal–organic framework (MOF) in water, resulting in non-negligible amounts of metal (iron) and linker (terephthalic acid, H2BDC) leached out from MIL-53(Fe). The photocatalytic activity of MIL-53(Fe) under simulated solar radiation was studied using phenol and metoprolol as target pollutants. MIL-53(Fe) on its own removed less than 10% of the pollutants after 3 h of irradiation, while in the presence of ozone, persulfate or hydrogen peroxide, complete elimination of pollutants was achieved within 2 h of exposure to radiation. However, the presence of oxidants and the formation of some reaction intermediates (e.g., short-chain carboxylic acids) accelerated MIL-53(Fe) decarboxylation. The findings of this work suggest that MIL-53(Fe) should not be recommended as a heterogeneous photocatalyst for water treatment before carrying out a careful evaluation of its stability under actual reaction conditions. Date A point or period of time associated with an event in the lifecycle of the resource 2021 Subject The topic of the resource MIL-53(Fe), Water Treatment, catalyst stability, metal-organic frameworks, photocatalysis, solar radiation Identifier An unambiguous reference to the resource within a given context 10.3390/catal11040448 Source A related resource from which the described resource is derived Catalysts Publisher An entity responsible for making the resource available MDPI AG Coverage The spatial or temporal topic of the resource, the spatial applicability of the resource, or the jurisdiction under which the resource is relevant Chemistry, Chemical technology Relation A related resource <a href="https://www.mdpi.com/2073-4344/11/4/448" target="_blank" rel="noreferrer noopener">https://www.mdpi.com/2073-4344/11/4/448</a>